Literature DB >> 16018644

One-carbon homologation of N-sulfonylaziridines to allylic amines using dimethylsulfonium methylide.

David M Hodgson1, Matthew J Fleming, Steven J Stanway.   

Abstract

[reaction: see text]. Regio- and stereodefined allylic N-sulfonylamines are synthesized in high yields and under experimentally straightforward conditions by reaction of N-sulfonylaziridines with excess dimethylsulfonium methylide.

Entities:  

Year:  2005        PMID: 16018644     DOI: 10.1021/ol051124p

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  β-Elimination of an Aziridine to an Allylic Amine: A Mechanistic Study.

Authors:  Kathleen M Morgan; Garry Brown; Monique A Pichon; Geannette Y Green
Journal:  J Phys Org Chem       Date:  2011-12       Impact factor: 2.391

  1 in total

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