Literature DB >> 16018623

1,2-Eliminations in a novel reductive coupling of nitroarenes to give azoxy arenes by sodium bis(trimethylsilyl)amide.

Jih Ru Hwu1, Asish R Das, Chia Wei Yang, Jiann-Jyh Huang, Ming-Hua Hsu.   

Abstract

[reaction: see text]. Symmetric azoxy arenes were successfully prepared in one step from 2 equiv of the corresponding nitroarenes by use of sodium bis(trimethylsilyl)amide as the deoxygenating agents in THF at 150 degrees C in a sealed tube.

Entities:  

Year:  2005        PMID： 16018623     DOI： 10.1021/ol050924x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Atomic engineering of high-density isolated Co atoms on graphene with proximal-atom controlled reaction selectivity.

Authors:  Huan Yan; Xiaoxu Zhao; Na Guo; Zhiyang Lyu; Yonghua Du; Shibo Xi; Rui Guo; Cheng Chen; Zhongxin Chen; Wei Liu; Chuanhao Yao; Jing Li; Stephen J Pennycook; Wei Chen; Chenliang Su; Chun Zhang; Jiong Lu
Journal:  Nat Commun       Date:  2018-08-23       Impact factor: 14.919

2.  Immobilized antimony species on magnetite: a novel and highly efficient magnetically reusable nanocatalyst for direct and gram-scale reductive-coupling of nitroarenes to azoarenes.

Authors:  Behzad Zeynizadeh; Fariba Faraji
Journal:  RSC Adv       Date:  2019-04-29       Impact factor: 3.361
  2 in total

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