Literature DB >> 16010350

Recent experimental and theoretical developments towards the observation of parity violation (PV) effects in molecules by spectroscopy.

Jeanne Crassous1, Christian Chardonnet, Trond Saue, Peter Schwerdtfeger.   

Abstract

Parity violation (PV) at the molecular level is known to be responsible for a tiny energy difference between the two enantiomers of a chiral molecule. This parity violation energy difference (PVED) has not yet been detected by experiment. In the last few years, the search for PV effects in molecules has made important steps ahead for several reasons. On one hand, very accurate infra-red spectroscopy measurements were performed by metrologists on bromochlorofluoromethane (CHFClBr) with a 10 Hz accuracy, which so far is the most precise. On the other hand, relativistic calculations were used for the evaluation of DeltaE(PV) allowing for a screening of favorable molecules for future measurements. The synthesis of such chiral molecules with high parity violation effects is currently being investigated. In memory of Professor Jean-Bernard Robert.

Entities:  

Year:  2005        PMID: 16010350     DOI: 10.1039/b504212g

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  3 in total

1.  Parity-violation energy of biomolecules-IV: protein secondary structure.

Authors:  Francesco Faglioni; Inmaculada García Cuesta
Journal:  Orig Life Evol Biosph       Date:  2010-12-16       Impact factor: 1.950

2.  A relativistic neutron fireball from a supernova explosion as a possible source of chiral influence.

Authors:  G A Gusev; T Saito; V A Tsarev; A V Uryson
Journal:  Orig Life Evol Biosph       Date:  2007-03-06       Impact factor: 1.120

Review 3.  The self-disproportionation of enantiomers (SDE): a menace or an opportunity?

Authors:  Jianlin Han; Osamu Kitagawa; Alicja Wzorek; Karel D Klika; Vadim A Soloshonok
Journal:  Chem Sci       Date:  2018-01-15       Impact factor: 9.825

  3 in total

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