Literature DB >> 16004418

Solvent-free process to esterify polysaccharides.

Atanu Biswas1, R L Shogren, J L Willett.   

Abstract

A novel process for the preparation of acetates of polysaccharides is described herein. The process involves the acetylation of polysaccharides with acetic anhydride in the presence of iodine as a catalyst. No solvent is required to bring about the acetylation. The method is simple, rapid, and characterized by a high conversion ratio. Conversion of cellulose and starch into their corresponding acetate derivatives has been demonstrated.

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Year:  2005        PMID: 16004418     DOI: 10.1021/bm0501757

Source DB:  PubMed          Journal:  Biomacromolecules        ISSN: 1525-7797            Impact factor:   6.988


  2 in total

1.  Microwave-assisted solvent-free acetylation of cellulose with acetic anhydride in the presence of iodine as a catalyst.

Authors:  Jing Li; Li-Ping Zhang; Feng Peng; Jing Bian; Tong-Qi Yuan; Feng Xu; Run-Cang Sun
Journal:  Molecules       Date:  2009-09-11       Impact factor: 4.411

2.  Milling in Seconds Accelerates Acetylation of Cellulose in Hours.

Authors:  Bungo Ochiai; Toshiya Watanabe; Chikako Hanzawa; Koki Akiyama; Yoshimasa Matsumura; Ryoichiro Shimura; Tomonori Koda; Akihiro Nishioka
Journal:  ACS Omega       Date:  2019-10-09
  2 in total

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