Literature DB >> 15997278

Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate.

Arjun Mendiratta1, Joshua S Figueroa, Christopher C Cummins.   

Abstract

Deprotonation of the titanium formate complex [Ar(t-Bu)N]3TiOC(O)H with LiN(i-Pr)2 resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt.

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Year:  2005        PMID： 15997278     DOI： 10.1039/b504492h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Redox chemistry and H-atom abstraction reactivity of a terminal zirconium(iv) oxo compound mediated by an appended cobalt(i) center.

Authors:  Hongtu Zhang; Gregory P Hatzis; Diane A Dickie; Curtis E Moore; Christine M Thomas
Journal:  Chem Sci       Date:  2020-09-04       Impact factor: 9.825
  1 in total

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