Literature DB >> 15997059

Diacetatobis(2-aminobenzothiazole-kappaN)cobalt(II).

Hümeyra Bati1, Hanife Saraçoĝlu, Nezihe Calişkan, Serkan Soylu.   

Abstract

The title complex, [Co(C2H3O2)2(C7H6N2S)2], contains a Co centre with a slightly distorted tetrahedral coordination geometry, involving two acetate ligands and two N atoms from the thiazole moiety [Co-O = 2.0025 (14) and 1.9953 (16) A, and Co-N = 2.0524 (18) and 2.0568 (18) A]. The interplanar angle between the two benzothiazole moieties is 77.86 (3) degrees . The amine groups, acting as donors, participate in intra- and intermolecular N-H...O hydrogen bonds, with N...O distances in the range 2.806 (2)-2.857 (2) A.

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Year:  2005        PMID: 15997059     DOI: 10.1107/S0108270105016811

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  2-Amino-benzothia-zolium 2,4-dicarboxy-benzoate monohydrate.

Authors:  Na Zhang; Kai-Sheng Liu; Xiao-Jun Zhao
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-05-23
  1 in total

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