Literature DB >> 15984842

Synthesis, structure, and spectroscopy of an oxodiiron(II) complex.

Nathan A Eckert1, Sebastian Stoian, Jeremy M Smith, Emile L Bominaar, Eckard Münck, Patrick L Holland.   

Abstract

Bridging oxo species are important in the synthetic and biological chemistry of iron, and are found with iron oxidation states from +2 to +4. We report the first oxodiiron(II) complex that has been crystallographically characterized. It has been examined by NMR, IR, and Mössbauer spectroscopies as well as density-functional calculations.

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Year:  2005        PMID： 15984842     DOI： 10.1021/ja0436704

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  An iron(ii) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity.

Authors:  Henrike Gehring; Ramona Metzinger; Beatrice Braun; Christian Herwig; Sjoerd Harder; Kallol Ray; Christian Limberg
Journal:  Dalton Trans       Date:  2016-01-13       Impact factor: 4.390

2.  Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes.

Authors:  Javier Vela; Jordi Cirera; Jeremy M Smith; Rene J Lachicotte; Christine J Flaschenriem; Santiago Alvarez; Patrick L Holland
Journal:  Inorg Chem       Date:  2007-01-08       Impact factor: 5.165

3.  New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H(2).

Authors:  Thomas R Dugan; Patrick L Holland
Journal:  J Organomet Chem       Date:  2009-08       Impact factor: 2.369

4.  Iron-sulfur repair YtfE protein from Escherichia coli: structural characterization of the di-iron center.

Authors:  Smilja Todorovic; Marta C Justino; Gerd Wellenreuther; Peter Hildebrandt; Daniel H Murgida; Wolfram Meyer-Klaucke; Lígia M Saraiva
Journal:  J Biol Inorg Chem       Date:  2008-03-21       Impact factor: 3.358

5.  The reactivity patterns of low-coordinate iron-hydride complexes.

Authors:  Ying Yu; Azwana R Sadique; Jeremy M Smith; Thomas R Dugan; Ryan E Cowley; William W Brennessel; Christine J Flaschenriem; Eckhard Bill; Thomas R Cundari; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2008-04-30       Impact factor: 15.419

6.  Reduction of CO2 to CO using low-coordinate iron: formation of a four-coordinate iron dicarbonyl complex and a bridging carbonate complex.

Authors:  Azwana R Sadique; William W Brennessel; Patrick L Holland
Journal:  Inorg Chem       Date:  2008-01-03       Impact factor: 5.165

Review 7.  Electronic structure and reactivity of three-coordinate iron complexes.

Authors:  Patrick L Holland
Journal:  Acc Chem Res       Date:  2008-07-23       Impact factor: 22.384

8.  Diiron oxo reactivity in a weak-field environment.

Authors:  Elizabeth J Johnson; Claudia Kleinlein; Rebecca A Musgrave; Theodore A Betley
Journal:  Chem Sci       Date:  2019-05-09       Impact factor: 9.825

9.  Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexes.

Authors:  Thomas R Dugan; Eckhard Bill; K Cory MacLeod; William W Brennessel; Patrick L Holland
Journal:  Inorg Chem       Date:  2014-02-20       Impact factor: 5.165
  9 in total

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