Literature DB >> 15983661

Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues.

Karena W Chapman1, Peter D Southon, Colin L Weeks, Cameron J Kepert.   

Abstract

The family of dehydrated nanoporous Prussian Blue analogues, M(II)3[Co(III)(CN)6]2 (M(II) = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.

Entities:  

Year:  2005        PMID: 15983661     DOI: 10.1039/b502850g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

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