Literature DB >> 15974791

Morphological structures formed by grafted polymers in poor solvents.

Sudip K Pattanayek1, T T Pham, G G Pereira.   

Abstract

We study a system of grafted polymers in a poor solvent by self-consistent-field methods as well as Monte-Carlo simulation methods. We observe a number of different morphological structures including an inverted solvent micelle or hole in the polymer layer, a lamella-like micelle structure, and fused, spherical micelle structures. These structures can be obtained by either varying the grafting density or chain length. We also develop a scaling theory for the existence of these structures and find reasonable agreement between this theory and our numerical calculations.

Entities:  

Year:  2005        PMID: 15974791     DOI: 10.1063/1.1917772

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  3 in total

1.  Polymer-decorated tethered membranes under good- and poor-solvent conditions.

Authors:  M Werner; J-U Sommer
Journal:  Eur Phys J E Soft Matter       Date:  2010-04       Impact factor: 1.890

2.  Self-organization of grafted polyelectrolyte layers via the coupling of chemical equilibrium and physical interactions.

Authors:  Mario Tagliazucchi; Mónica Olvera de la Cruz; Igal Szleifer
Journal:  Proc Natl Acad Sci U S A       Date:  2010-03-04       Impact factor: 11.205

3.  Lamellae-Parking Garage Structure-Lamellae Transition in Densely Grafted Layers of Amphiphilic Homopolymers: Impact of Polymerization Degree.

Authors:  Alexei A Lazutin; Valentina V Vasilevskaya
Journal:  ACS Omega       Date:  2018-10-10
  3 in total

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