| Literature DB >> 15974791 |
Sudip K Pattanayek1, T T Pham, G G Pereira.
Abstract
We study a system of grafted polymers in a poor solvent by self-consistent-field methods as well as Monte-Carlo simulation methods. We observe a number of different morphological structures including an inverted solvent micelle or hole in the polymer layer, a lamella-like micelle structure, and fused, spherical micelle structures. These structures can be obtained by either varying the grafting density or chain length. We also develop a scaling theory for the existence of these structures and find reasonable agreement between this theory and our numerical calculations.Entities:
Year: 2005 PMID: 15974791 DOI: 10.1063/1.1917772
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488