Literature DB >> 15968350

[{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]36-: a molecular quantum spin icosidodecahedron.

Bogdan Botar1, Paul Kögerler, Craig L Hill.   

Abstract

Self-assembly of aqueous solutions of molybdate and vanadate under reducing, mildly acidic conditions results in a polyoxomolybdate-based {Mo72V30} cluster compound Na8K16(VO)(H2O)5[K10 subset{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20].150H2O, 1, a quantum spin-based Keplerate structure.

Entities:  

Year:  2005        PMID: 15968350     DOI: 10.1039/b504491j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Regioselective synthesis and characterization of monovanadium-substituted β-octamolybdate [VMo7O26]5.

Authors:  Lukáš Krivosudský; Alexander Roller; Annette Rompel
Journal:  Acta Crystallogr C Struct Chem       Date:  2019-06-07       Impact factor: 1.172

  1 in total

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