| Literature DB >> 15962944 |
Kenneth Dedeian1, Jianmin Shi, Nigel Shepherd, Eric Forsythe, David C Morton.
Abstract
Mixed (difluoro)phenylpyridine/(difluoro)phenylpyrazole tris-cyclometalated iridium complexes were prepared in order to study the effect of fluorination and the pyridine/pyrazole ratio on the emission and electrochemical properties. Increasing fluorination and replacement of pyridine by pyrazole both leads to a widening of the HOMO-LUMO gap and generally leads to a blue shift in emission.Entities:
Year: 2005 PMID: 15962944 DOI: 10.1021/ic050324u
Source DB: PubMed Journal: Inorg Chem ISSN: 0020-1669 Impact factor: 5.165