Literature DB >> 15962041

Easy hydrolysis of white phosphorus coordinated to ruthenium.

Massimo Di Vaira1, Piero Frediani, Stefano Seniori Costantini, Maurizio Peruzzini, Piero Stoppioni.   

Abstract

The P4 molecule bound to ruthenium as an eta1-ligand in [CpRu(PPh3)2(eta1-P4)]Y (Y = PF6, CF3SO3) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3, which remains coordinated to the [CpRu(PPh3)2] fragment, and oxygenated derivatives.

Entities:  

Year:  2005        PMID: 15962041     DOI: 10.1039/b504795a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  3 in total

Review 1.  Functionalization of Pentaphosphorus Cations by Complexation.

Authors:  Anup K Adhikari; Christoph G P Ziegler; Kai Schwedtmann; Clemens Taube; Jan J Weigand; Robert Wolf
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-06       Impact factor: 15.336

Review 2.  Transition-Metal-Mediated Functionalization of White Phosphorus.

Authors:  Christian M Hoidn; Daniel J Scott; Robert Wolf
Journal:  Chemistry       Date:  2020-11-18       Impact factor: 5.236

3.  Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt.

Authors:  Christoph G P Ziegler; Thomas M Maier; Stefan Pelties; Clemens Taube; Felix Hennersdorf; Andreas W Ehlers; Jan J Weigand; Robert Wolf
Journal:  Chem Sci       Date:  2018-12-04       Impact factor: 9.825

  3 in total

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