| Literature DB >> 15957942 |
Gregory R Cook1, Robert Kargbo, Bikash Maity.
Abstract
[reaction: see text] A facile and highly selective indium-mediated allylation of hydrazones utilizing BINOL ligands is described. Chiral (R)-3,3'-bistrifluoromethylBINOL afforded homoallylic amines in up to 97% ee with stoichiometric ligand. Employing only 10 mol % ligand afforded selectivity of up to 92% ee.Entities:
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Year: 2005 PMID： 15957942 DOI： 10.1021/ol051160o
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005