Literature DB >> 15957023

Ethene hydroformylation with CO/H2O: nucleophilic attack by water on to a terminal CO of a Ru(II) acylcarbonyl complex.

Giuseppe Fachinetti1, Tiziana Funaioli, Fabio Marchetti.   

Abstract

The reaction with water of acyldicarbonyl-Ru(II) complexes relevant to ruthenium catalysed ethene hydrocarbonylation with CO/H2O is shown to consist of a nucleophilic attack and to proceed via coordination of propionate and CO to the Ru(II) species.

Entities:  

Year:  2005        PMID: 15957023     DOI: 10.1039/b502998h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis.

Authors:  Andrea Ambrosi; Scott E Denmark
Journal:  Angew Chem Int Ed Engl       Date:  2016-09-06       Impact factor: 15.336

  1 in total

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