| Literature DB >> 15954755 |
Scott L Cockroft1, Christopher A Hunter, Kevin R Lawson, Julie Perkins, Christopher J Urch.
Abstract
A supramolecular approach has been used to investigate the free energies of intermolecular aromatic stacking interactions. Chemical double mutant cycles have been used to measure the effect of a range of substituents on face-to-face stacking interactions with phenyl and pentafluorophenyl rings. Electrostatic effects dominate the trends in interaction energy.Mesh:
Substances:
Year: 2005 PMID: 15954755 DOI: 10.1021/ja050880n
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419