| Literature DB >> 15941233 |
Pik Ying Chan1, Wai Ming Kwok, Sze Kui Lam, Pauline Chiu, David Lee Phillips.
Abstract
Time-resolved resonance Raman spectroscopy was used to directly observe the reaction of the 2-fluorenylnitrenium ion with guanosine to produce a C8 intermediate species. Comparison of the Raman spectra with results of density functional theory calculations indicates the C8 intermediate forms two C=N conjugated bonds in ring 1 of the guanosine moiety.Entities:
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Year: 2005 PMID： 15941233 DOI： 10.1021/ja0505651
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419