Literature DB >> 15932313

Nucleophilic trifluoromethylation of imines using the CF3I/TDAE reagent.

Wei Xu1, William R Dolbier.   

Abstract

The nucleophilic trifluoromethylation reagent derived from CF3I and tetrakis(dimethylamino)ethylene (TDAE) was found to be effective in addition to both N-tosyl aldimines and N-tolyl sulfinimines, the latter reaction exhibiting very good diastereoselectivity.

Entities:  

Year:  2005        PMID： 15932313     DOI： 10.1021/jo050483v

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Nucleophilic trifluoromethylation of carbonyl compounds: trifluoroacetaldehyde hydrate as a trifluoromethyl source.

Authors:  G K Surya Prakash; Zhe Zhang; Fang Wang; Socrates Munoz; George A Olah
Journal:  J Org Chem       Date:  2013-02-28       Impact factor: 4.354

2.  Discovery and development of organic super-electron-donors.

Authors:  John A Murphy
Journal:  J Org Chem       Date:  2014-03-25       Impact factor: 4.354

3.  Reduction of arenediazonium salts by tetrakis(dimethylamino)ethylene (TDAE): efficient formation of products derived from aryl radicals.

Authors:  Mohan Mahesh; John A Murphy; Franck LeStrat; Hans Peter Wessel
Journal:  Beilstein J Org Chem       Date:  2009-01-12       Impact factor: 2.883
  3 in total

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