Literature DB >> 15932214

Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes providing nitriles.

Takahiro Nishimura1, Tomoaki Yoshinaka, Yoshiki Nishiguchi, Yasunari Maeda, Sakae Uemura.   

Abstract

[reaction: see text] Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes in the presence of 9,10-dihydroanthracene and potassium carbonate proceeds to give saturated nitriles via C-C bond fission at the sterically more hindered site.

Entities:  

Year:  2005        PMID： 15932214     DOI： 10.1021/ol0507120

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

Review 1.  Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis.

Authors:  Kitae Kwon; R Thomas Simons; Meganathan Nandakumar; Jennifer L Roizen
Journal:  Chem Rev       Date:  2021-10-08       Impact factor: 60.622

2.  Transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters.

Authors:  Jin-Jiang Zhang; Xin-Hua Duan; Yong Wu; Jun-Cheng Yang; Li-Na Guo
Journal:  Chem Sci       Date:  2018-10-02       Impact factor: 9.825

3.  Functionalization of remote C(sp3)-H bonds enabled by copper-catalyzed coupling of O-acyloximes with terminal alkynes.

Authors:  Zhaodong Li; Rubén O Torres-Ochoa; Qian Wang; Jieping Zhu
Journal:  Nat Commun       Date:  2020-01-21       Impact factor: 14.919

4.  Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers.

Authors:  Franck Le Vaillant; Marion Garreau; Stefano Nicolai; Ganna Gryn'ova; Clemence Corminboeuf; Jerome Waser
Journal:  Chem Sci       Date:  2018-05-30       Impact factor: 9.825
  4 in total

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