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Literature DB >> 15928777

Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones.

Alexandre Alexakis¹, Victoria Albrow, Kallolmay Biswas, Magali d'Augustin, Oscar Prieto, Simon Woodward.

Abstract

Simple phosphoramidite ligands afford good to excellent levels of enantioselectivity in 1,4-additions of AlR3 species to enones; sequential carboalumination-ACA cascades are possible.

Entities: Chemical

Year: 2005 PMID： 15928777 DOI： 10.1039/b503074a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS.

Authors: Craig R Smith; Daniel J Mans; T V Rajanbabu; Scott E Denmark; Son T Nguyen
Journal: Organic Synth Date: 2008

2. Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents.

Authors: Rebecca M Maksymowicz; Philippe M C Roth; Stephen P Fletcher
Journal: Nat Chem Date: 2012-07-15 Impact factor: 24.427

3. Synthesis and characterization of privileged monodentate phosphoramidite ligands and chiral Brønsted acids derived from d-mannitol.

Authors: Abdullah Mohammed A Al-Majid; Assem Barakat; Yahia Nasser Mabkhot; Mohammad Shahidul Islam
Journal: Int J Mol Sci Date: 2012-02-29 Impact factor: 6.208

Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones.

1. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS.

2. Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents.

3. Synthesis and characterization of privileged monodentate phosphoramidite ligands and chiral Brønsted acids derived from d-mannitol.

4. Rhodium(I)-Complexes Catalyzed 1,4-Conjugate Addition of Arylzinc Chlorides to N-Boc-4-pyridone.

5. First Synthesis of (-)-Altenuene-D₃ Suitable as Internal Standard for Isotope Dilution Mass Spectrometry.

Review 6. Recent Achievements in Total Synthesis for Integral Structural Revisions of Marine Natural Products.

Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones.

1. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS.

2. Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents.

3. Synthesis and characterization of privileged monodentate phosphoramidite ligands and chiral Brønsted acids derived from d-mannitol.

4. Rhodium(I)-Complexes Catalyzed 1,4-Conjugate Addition of Arylzinc Chlorides to N-Boc-4-pyridone.

5. First Synthesis of (-)-Altenuene-D3 Suitable as Internal Standard for Isotope Dilution Mass Spectrometry.

Review 6. Recent Achievements in Total Synthesis for Integral Structural Revisions of Marine Natural Products.

5. First Synthesis of (-)-Altenuene-D₃ Suitable as Internal Standard for Isotope Dilution Mass Spectrometry.