| Literature DB >> 15917933 |
Ting Dong1, Jiang Li, Fan Huang, Lian Wang, Jing Tu, Yoshifumi Torimoto, Masayoshi Sadakata, Quanxin Li.
Abstract
A novel approach to the direct synthesis of phenol from benzene was obtained with high benzene conversion (30%) and phenol selectivity (approximately 90%) by using a microporous material [Ca24Al28O64]4+.4O-(C12A7-O-) as catalyst with oxygen and water; active O- and OH- anions are proposed to play important roles in the formation of phenol by hydroxylating the aromatic ring of benzene.Entities:
Year: 2005 PMID： 15917933 DOI： 10.1039/b419206k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222