Literature DB >> 15917930

Tin-catalyzed conversion of trioses to alkyl lactates in alcohol solution.

Yukiko Hayashi1, Yoshiyuki Sasaki.   

Abstract

Tin chlorides, SnCl2 and SnCl4.5H2O are excellent catalysts for the reactions of trioses, dihydroxyacetone and glyceraldehyde with alcohols (MeOH, EtOH and nBuOH) to give alkyl lactates, whose reaction mechanism involves the intermediary formation of pyruvic aldehyde followed by its esterification, which is distinctively promoted by tin halides.

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Year:  2005        PMID： 15917930     DOI： 10.1039/b501964h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Tandem catalysis for the production of alkyl lactates from ketohexoses at moderate temperatures.

Authors:  Marat Orazov; Mark E Davis
Journal:  Proc Natl Acad Sci U S A       Date:  2015-09-08       Impact factor: 11.205

2.  Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water.

Authors:  Manuel Moliner; Yuriy Román-Leshkov; Mark E Davis
Journal:  Proc Natl Acad Sci U S A       Date:  2010-03-22       Impact factor: 11.205

3.  Development of New Carbon Resources: Production of Important Chemicals from Algal Residue.

Authors:  Sho Yamaguchi; Yuuki Kawada; Hidetaka Yuge; Kan Tanaka; Sousuke Imamura
Journal:  Sci Rep       Date:  2017-04-12       Impact factor: 4.379

4.  One-pot conversion of dihydroxyacetone into ethyl lactate by Zr-based catalysts.

Authors:  Junjun Shi; Fukun Li; Jie Zhang; Ning Li; Xingmin Wang; Xianming Zhang; Yunqi Liu
Journal:  RSC Adv       Date:  2021-03-15       Impact factor: 3.361

5.  Mesoporous Sn-In-MCM-41 Catalysts for the Selective Sugar Conversion to Methyl Lactate and Comparative Life Cycle Assessment with the Biochemical Process.

Authors:  Óscar de la Iglesia; Miryan Sarango; Mikel Munárriz; Magdalena Malankowska; Alberto Navajas; Luis M Gandía; Joaquín Coronas; Carlos Téllez
Journal:  ACS Sustain Chem Eng       Date:  2022-02-21       Impact factor: 8.198

6.  Synergetic effects of bimetals in modified beta zeolite for lactic acid synthesis from biomass-derived carbohydrates.

Authors:  Meng Xia; Wenjie Dong; Minyan Gu; Cheng Chang; Zheng Shen; Yalei Zhang
Journal:  RSC Adv       Date:  2018-02-28       Impact factor: 3.361
  6 in total

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