Literature DB >> 15917913

Optical properties of donor-acceptor phenylene-ethynylene systems containing the 6-methylpyran-2-one group as an acceptor.

Jonathan C Collings1, Alexander C Parsons, Laurent Porrès, Andrew Beeby, Andrei S Batsanov, Judith A K Howard, Donocadh P Lydon, Paul J Low, Ian J S Fairlamb, Todd B Marder.   

Abstract

Donor-acceptor phenylene ethynylene systems containing the 6-methylpyran-2-one group, synthesized via classic or microwave-assisted Sonogashira cross-coupling, exhibit pronounced solvatochromism in fluorescence suggesting a highly polar excited state; 4-[4-(4-N,N-dihexylaminophenylethynyl)phenylethynyl]-6-methylpyran-2-one has a fluorescence quantum yield >0.9 in cyclohexane.

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Year:  2005        PMID： 15917913     DOI： 10.1039/b502781k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Controlled microwave heating in modern organic synthesis: highlights from the 2004-2008 literature.

Authors:  C Oliver Kappe; Doris Dallinger
Journal:  Mol Divers       Date:  2009-04-21       Impact factor: 2.943

2.  Tandem fluorescence and Raman (fluoRaman) characterisation of a novel photosensitiser in colorectal cancer cell line SW480.

Authors:  Julia Gala de Pablo; David R Chisholm; Andreas Steffen; Amanda K Nelson; Christoph Mahler; Todd B Marder; Sally A Peyman; John M Girkin; Carrie A Ambler; Andrew Whiting; Stephen D Evans
Journal:  Analyst       Date:  2018-12-03       Impact factor: 4.616

3.  Photoactivated cell-killing involving a low molecular weight, donor-acceptor diphenylacetylene.

Authors:  David R Chisholm; Rebecca Lamb; Tommy Pallett; Valerie Affleck; Claire Holden; Joanne Marrison; Peter O'Toole; Peter D Ashton; Katherine Newling; Andreas Steffen; Amanda K Nelson; Christoph Mahler; Roy Valentine; Thomas S Blacker; Angus J Bain; John Girkin; Todd B Marder; Andrew Whiting; Carrie A Ambler
Journal:  Chem Sci       Date:  2019-03-21       Impact factor: 9.825
  3 in total

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