Superconductivity in charge Kondo systems.

We present a theory for superconductivity and charge Kondo fluctuations, i.e., resonant quantum valence fluctuations by two charge units, for Tl-doped PbTe. We show that Tl is very special as it first supplies a certain amount of charge carriers to the PbTe-valence band and then puts itself into a self-tuned resonant state to yield a new, robust pairing mechanism for these carriers.