Literature DB >> 15901165

Ni(II)-catalyzed Conia-ene reaction of 1,3-dicarbonyl compounds with alkynes.

Qiang Gao1, Bao-Fu Zheng, Jin-Heng Li, Dan Yang.   

Abstract

[reaction: see text]. We have discovered a Ni(II)-catalyzed Conia-ene reaction of 1,3-dicarbonyl compounds with alkynes. In the presence of Ni(acac)2 and Yb(OTf)3, various acetylenic 1,3-dicarbonyl compounds underwent Conia-ene reaction to give mono- and bicyclic olefinic cyclopentanes. A mechanism involving the enol-yne-Ni complex formation is proposed and supported by deuterium-labeling experiments.

Entities:  

Year:  2005        PMID： 15901165     DOI： 10.1021/ol050532q

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Palladium-catalyzed carbocyclization of alkynyl ketones proceeding through a carbopalladation pathway.

Authors:  Natalia Chernyak; Serge I Gorelsky; Vladimir Gevorgyan
Journal:  Angew Chem Int Ed Engl       Date:  2011-02-07       Impact factor: 15.336

2.  A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.

Authors:  Nathan D Shapiro; F Dean Toste
Journal:  Synlett       Date:  2010-03-01       Impact factor: 2.454

3.  Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,N'-dioxide-indium(III) or nickel(II) synergistic catalysis.

Authors:  Xinyue Hu; Xiaoxue Tang; Xiying Zhang; Lili Lin; Xiaoming Feng
Journal:  Nat Commun       Date:  2021-05-21       Impact factor: 14.919
  3 in total

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