Literature DB >> 15898776

Radical addition to "cation pool". Reverse process of radical cation fragmentation.

Tomokazu Maruyama1, Seiji Suga, Jun-ichi Yoshida.   

Abstract

The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.

Entities:  

Year:  2005        PMID： 15898776     DOI： 10.1021/ja0511218

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Cu-catalyzed cross-dehydrogenative coupling: a versatile strategy for C-C bond formations via the oxidative activation of sp(3) C-H bonds.

Authors:  Zhiping Li; D Scott Bohle; Chao-Jun Li
Journal:  Proc Natl Acad Sci U S A       Date:  2006-06-05       Impact factor: 11.205

2.  Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance.

Authors:  Ming Yan; Yu Kawamata; Phil S Baran
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

3.  Electrochemical generation of glycosyl triflate pools.

Authors:  Toshiki Nokami; Akito Shibuya; Hiroaki Tsuyama; Seiji Suga; Albert A Bowers; David Crich; Jun-ichi Yoshida
Journal:  J Am Chem Soc       Date:  2007-08-14       Impact factor: 15.419

Review 4.  The Shono-type electroorganic oxidation of unfunctionalised amides. Carbon-carbon bond formation via electrogenerated N-acyliminium ions.

Authors:  Alan M Jones; Craig E Banks
Journal:  Beilstein J Org Chem       Date:  2014-12-18       Impact factor: 2.883

5.  Redox active dendronized polystyrenes equipped with peripheral triarylamines.

Authors:  Toshiki Nokami; Naoki Musya; Tatsuya Morofuji; Keiji Takeda; Masahiro Takumi; Akihiro Shimizu; Jun-Ichi Yoshida
Journal:  Beilstein J Org Chem       Date:  2014-12-22       Impact factor: 2.883

6.  Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.

Authors:  Toshiki Nokami; Ryoji Soma; Yoshimasa Yamamoto; Toshiyuki Kamei; Kenichiro Itami; Jun-Ichi Yoshida
Journal:  Beilstein J Org Chem       Date:  2007-02-08       Impact factor: 2.883
  6 in total

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