Literature DB >> 15898770

Persistent (amino)(silyl)carbenes.

Yves Canac1, Salvador Conejero, Bruno Donnadieu, Wolfgand W Schoeller, Guy Bertrand.   

Abstract

(Amino)(silyl)carbenes, prepared by substitution reactions at a carbene center, can survive several days at 0 degrees C. These species are not push-pull carbenes as their phosphino analogues and therefore are excellent ligands for transition-metal centers.

Entities:  

Year:  2005        PMID: 15898770     DOI: 10.1021/ja051109f

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  3 in total

1.  A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes.

Authors:  Vincent Lavallo; Yves Canac; Alan DeHope; Bruno Donnadieu; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2005-11-11       Impact factor: 15.336

2.  Three-Component Visible-Light-Induced Palladium-Catalyzed 1,2-Alkyl Carbamoylation/Cyanation of Alkenes.

Authors:  Xiangqing Jia; Ziyan Zhang; Vladimir Gevorgyan
Journal:  ACS Catal       Date:  2021-10-15       Impact factor: 13.700

3.  An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene.

Authors:  Joan Vignolle; Bruno Donnadieu; Didier Bourissou; Guy Bertrand
Journal:  Tetrahedron Lett       Date:  2007       Impact factor: 2.415

  3 in total

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