Literature DB >> 15898746

Osmium diboride, an ultra-incompressible, hard material.

Robert W Cumberland1, Michelle B Weinberger, John J Gilman, Simon M Clark, Sarah H Tolbert, Richard B Kaner.   

Abstract

The need for wear- and scratch-resistant materials drives the quest for new superhard materials. In this work, we apply two design parameters to identify ultra-incompressible, superhard materials-high valence electron density and high bond covalency. Our first example of such a material is OsB2. The bulk modulus of OsB2 was measured using in situ high-pressure X-ray diffraction and was determined to be in the range of 365-395 GPa. While this value is slightly less than that of the bulk modulus of diamond, due to the anisotropic crystal structure of OsB2, the axis compressibility in the orthorhombic c-direction is less than the axis compressibility found in diamond. OsB2 also scratches the surface of a sapphire window, indicating that the hardness of OsB2 exceeds 2000 kg/mm2.

Entities:  

Year:  2005        PMID: 15898746     DOI: 10.1021/ja043806y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  24 in total

1.  Reduction of the bulk modulus at high pressure in CrN.

Authors:  Francisco Rivadulla; Manuel Bañobre-López; Camilo X Quintela; Alberto Piñeiro; Victor Pardo; Daniel Baldomir; Manuel Arturo López-Quintela; José Rivas; Carlos A Ramos; Horacio Salva; Jian-Shi Zhou; John B Goodenough
Journal:  Nat Mater       Date:  2009-10-25       Impact factor: 43.841

2.  Structure of superhard tungsten tetraboride: a missing link between MB2 and MB12 higher borides.

Authors:  Andrew T Lech; Christopher L Turner; Reza Mohammadi; Sarah H Tolbert; Richard B Kaner
Journal:  Proc Natl Acad Sci U S A       Date:  2015-03-02       Impact factor: 11.205

3.  Tungsten tetraboride, an inexpensive superhard material.

Authors:  Reza Mohammadi; Andrew T Lech; Miao Xie; Beth E Weaver; Michael T Yeung; Sarah H Tolbert; Richard B Kaner
Journal:  Proc Natl Acad Sci U S A       Date:  2011-06-20       Impact factor: 11.205

4.  Structural, mechanical, and electronic properties of Rh2B and RhB2: first-principles calculations.

Authors:  Binhua Chu; Da Li; Fubo Tian; Defang Duan; Xiaojing Sha; Yunzhou Lv; Huadi Zhang; Bingbing Liu; Tian Cui
Journal:  Sci Rep       Date:  2015-06-30       Impact factor: 4.379

5.  Nitrogen concentration driving the hardness of rhenium nitrides.

Authors:  Zhonglong Zhao; Kuo Bao; Da Li; Defang Duan; Fubo Tian; Xilian Jin; Changbo Chen; Xiaoli Huang; Bingbing Liu; Tian Cui
Journal:  Sci Rep       Date:  2014-04-25       Impact factor: 4.379

6.  Polytypism in superhard transition-metal triborides.

Authors:  Yongcheng Liang; Jiong Yang; Xun Yuan; Wujie Qiu; Zheng Zhong; Jihui Yang; Wenqing Zhang
Journal:  Sci Rep       Date:  2014-05-27       Impact factor: 4.379

7.  A novel stable binary BeB₂ phase [corrected].

Authors:  Changzeng Fan; Ye Jin; Jian Li; Xu Dong
Journal:  Sci Rep       Date:  2014-11-11       Impact factor: 4.379

8.  Insight into the mechanical, thermodynamics and superconductor properties of NbRuB via first-principles calculation.

Authors:  Wenyan Tian; Haichuan Chen
Journal:  Sci Rep       Date:  2016-01-12       Impact factor: 4.379

9.  Influence of Content of Al2O3 on Structure and Properties of Nanocomposite Nb-B-Al-O films.

Authors:  Na Liu; Lei Dong; Lei Dong; Jiangang Yu; Yupeng Pan; Rongxin Wan; Hanqing Gu; Dejun Li
Journal:  Nanoscale Res Lett       Date:  2015-11-24       Impact factor: 4.703

10.  Crystal Field Splitting is Limiting the Stability and Strength of Ultra-incompressible Orthorhombic Transition Metal Tetraborides.

Authors:  R F Zhang; X D Wen; D Legut; Z H Fu; S Veprek; E Zurek; H K Mao
Journal:  Sci Rep       Date:  2016-03-15       Impact factor: 4.379

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