Literature DB >> 15884918

"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications.

Masayuki Okajima1, Seiji Suga, Kenichiro Itami, Jun-ichi Yoshida.   

Abstract

The "cation pools" of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.

Entities:  

Year:  2005        PMID： 15884918     DOI： 10.1021/ja050414y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance.

Authors:  Ming Yan; Yu Kawamata; Phil S Baran
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

2.  Electrochemical generation of glycosyl triflate pools.

Authors:  Toshiki Nokami; Akito Shibuya; Hiroaki Tsuyama; Seiji Suga; Albert A Bowers; David Crich; Jun-ichi Yoshida
Journal:  J Am Chem Soc       Date:  2007-08-14       Impact factor: 15.419

3.  Redox active dendronized polystyrenes equipped with peripheral triarylamines.

Authors:  Toshiki Nokami; Naoki Musya; Tatsuya Morofuji; Keiji Takeda; Masahiro Takumi; Akihiro Shimizu; Jun-Ichi Yoshida
Journal:  Beilstein J Org Chem       Date:  2014-12-22       Impact factor: 2.883

4.  Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles.

Authors:  Chen-Yan Cai; Hai-Chao Xu
Journal:  Nat Commun       Date:  2018-09-03       Impact factor: 14.919

5.  Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.

Authors:  Toshiki Nokami; Ryoji Soma; Yoshimasa Yamamoto; Toshiyuki Kamei; Kenichiro Itami; Jun-Ichi Yoshida
Journal:  Beilstein J Org Chem       Date:  2007-02-08       Impact factor: 2.883
  5 in total

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