| Literature DB >> 15877429 |
Maximilian Fichtner1, Christoph Frommen, Olaf Fuhr.
Abstract
Several ways to synthesize solvated and desolvated calcium tetrahydroaluminate by wet-chemical and mechanochemical methods are presented. The products were characterized by elemental analysis, X-ray diffraction (XRD), and infrared spectroscopy (FTIR). The crystal structure of Ca(AlH(4))(2).4THF was determined. After desolvation, an ultrafine powder was obtained. IR data and the mass balance suggest a compound with the composition Ca(AlH(4))(2), containing tetrahedral [AlH(4)] groups.Entities:
Year: 2005 PMID： 15877429 DOI： 10.1021/ic048291q
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165