Literature DB >> 15877417

A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex.

Jian-Kai Cheng1, Yu-Biao Chen, Ling Wu, Jian Zhang, Yi-Hang Wen, Zhao-Ji Li, Yuan-Gen Yao.   

Abstract

The solvothermal reaction of CuCl(2).2H(2)O with pyridine-4-thiol and ethanol yielded a novel photoluminescent 3-D polymeric complex with an interesting decorated diamondoid network that is constructed of decanuclear copper(I) cluster units and mu(4)-Cl ligands. The in situ generation of CuSO(4).5H(2)O implies the spontaneous occurrence of desulfurization and redox reactions in the present system.

Entities:  

Year:  2005        PMID: 15877417     DOI: 10.1021/ic050301f

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift.

Authors:  Bingjing Xin; Jianwei Sang; Yi Gao; Guanghua Li; Zhan Shi; Shouhua Feng
Journal:  RSC Adv       Date:  2018-01-08       Impact factor: 4.036

  1 in total

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