Literature DB >> 15876104

Novel deoxygenation reaction of epoxides by indium.

Mohan Mahesh1, John A Murphy, Hans Peter Wessel.   

Abstract

[reaction: see text] A novel, mild, ecofriendly protocol for the deoxygenation of epoxides to alkenes using indium metal and indium(I) chloride or ammonium chloride in alcohol has been developed. It was necessary for the presence of good radical-stabilizing groups adjacent to the oxirane ring for the deoxygenation reaction to occur. It is proposed that this reaction occurs through an SET process with indium as an electron donor.

Entities:  

Year:  2005        PMID： 15876104     DOI： 10.1021/jo047904d

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Reductions of challenging organic substrates by a nickel complex of a noninnocent crown carbene ligand.

Authors:  Neil J Findlay; Stuart R Park; Franziska Schoenebeck; Elise Cahard; Sheng-Ze Zhou; Leonard E A Berlouis; Mark D Spicer; Tell Tuttle; John A Murphy
Journal:  J Am Chem Soc       Date:  2010-11-10       Impact factor: 15.419

2.  Gold nanoparticle-catalyzed environmentally benign deoxygenation of epoxides to alkenes.

Authors:  Akifumi Noujima; Takato Mitsudome; Tomoo Mizugaki; Koichiro Jitsukawa; Kiyotomi Kaneda
Journal:  Molecules       Date:  2011-09-28       Impact factor: 4.411

3.  Deoxygenation of Epoxides with Carbon Monoxide.

Authors:  Theo Maulbetsch; Eva Jürgens; Doris Kunz
Journal:  Chemistry       Date:  2020-07-23       Impact factor: 5.236
  3 in total

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