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Literature DB >> 15876043

Synthesis of cis-fused carbo-bicycles by domino enyne cross-metathesis/intramolecular Diels-Alder Reaction.

Abstract

A sequential combination of Ru-catalyzed enyne cross-metathesis (EYCM) and intramolecular Diels-Alder reaction (IMDA) is described. Different terminal alkynes and alpha,omega-dienes obtained by a Baylis-Hillman reaction were transformed into substituted cis-hexahydro-1H-indenes and cis-hexahydro-2H-naphthalin-1-ones.

Entities: Chemical

Year: 2005 PMID： 15876043 DOI： 10.1021/ol050508c

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

2 in total

1. Ene-yne cross-metathesis with ruthenium carbene catalysts.

Authors: Cédric Fischmeister; Christian Bruneau
Journal: Beilstein J Org Chem Date: 2011-02-04 Impact factor: 2.883

2. Tandem cross enyne metathesis (CEYM)-intramolecular Diels-Alder reaction (IMDAR). An easy entry to linear bicyclic scaffolds.

Authors: Javier Miró; María Sánchez-Roselló; Álvaro Sanz; Fernando Rabasa; Carlos Del Pozo; Santos Fustero
Journal: Beilstein J Org Chem Date: 2015-08-25 Impact factor: 2.883

2 in total