| Literature DB >> 15876025 |
Gérard Cahiez1, Christophe Chaboche, Florence Mahuteau-Betzer, Mathieu Ahr.
Abstract
Iron-catalyzed homo-coupling of simple and functionalized arylmagnesium reagents is described. The reaction is highly chemoselective (CN, COOEt and NO(2) groups are tolerated). The procedure was used to perform intramolecular couplings. This cyclization reaction is the key step of the total synthesis of the N-methylcrinasiadine.Entities:
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Year: 2005 PMID: 15876025 DOI: 10.1021/ol050340v
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005