| Literature DB >> 15856107 |
Jean-Michel Senegas1, Sylvain Koeller, Gerald Bernardinelli, Claude Piguet.
Abstract
A thorough examination of the disassembly of bimetallic triple-stranded lanthanide helicates [Ln2(Li)3]6+ (stoichiometry S = m/n = 2/3 = 0.67, global complexity GC = m + n = 2 + 3 = 5) in excess of metals shows the competitive formation of standard linear bimetallic complexes [Ln2(Li)2]6+ (S= 1.0, GC = 4), and circular trimetallic single-stranded helicates [Ln3(Li)3]9+ (S= 1.0, GC = 6).Entities:
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Year: 2005 PMID： 15856107 DOI： 10.1039/b501399b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222