Literature DB >> 15846438

Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts.

Connie K Y Lee1, Andrew B Holmes, Steven V Ley, Ian F McConvey, Bushra Al-Duri, Gary A Leeke, Regina C D Santos, Jonathan P K Seville.   

Abstract

Suzuki cross-coupling reactions are effected in both conventional organic solvents, under continuous flow conditions at 70 degree C, and in batch mode in supercritical carbon dioxide (scCO2), at temperatures as low as 40 degrees C in the presence of palladium(II) acetate microencapsulated in polyurea [PdEnCat] and tetra-n-butylammonium salts.

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Year:  2005        PMID: 15846438     DOI: 10.1039/b418669a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  7 in total

1.  Polyionic polymers--heterogeneous media for metal nanoparticles as catalyst in Suzuki-Miyaura and Heck-Mizoroki reactions under flow conditions.

Authors:  Klaas Mennecke; Andreas Kirschning
Journal:  Beilstein J Org Chem       Date:  2009-05-08       Impact factor: 2.883

2.  Homocoupling of aryl halides in flow: Space integration of lithiation and FeCl(3) promoted homocoupling.

Authors:  Aiichiro Nagaki; Yuki Uesugi; Yutaka Tomida; Jun-Ichi Yoshida
Journal:  Beilstein J Org Chem       Date:  2011-08-02       Impact factor: 2.883

3.  Reactions of nitroxides 15. Cinnamates bearing a nitroxyl moiety synthesized using a Mizoroki-Heck cross-coupling reaction.

Authors:  Jerzy Zakrzewski; Bogumiła Huras
Journal:  Beilstein J Org Chem       Date:  2015-07-13       Impact factor: 2.883

4.  Polymeric glabrescione B nanocapsules for passive targeting of Hedgehog-dependent tumor therapy in vitro.

Authors:  Cinzia Ingallina; Pedro M Costa; Francesca Ghirga; Rebecca Klippstein; Julie T Wang; Simone Berardozzi; Naomi Hodgins; Paola Infante; Steven M Pollard; Bruno Botta; Khuloud T Al-Jamal
Journal:  Nanomedicine (Lond)       Date:  2017-03-21       Impact factor: 5.307

5.  Preparation of Metal-Immobilized Methacrylate-Based Monolithic Columns for Flow-Through Cross-Coupling Reactions.

Authors:  Akhmad Sabarudin; Shin Shu; Kazuhiro Yamamoto; Tomonari Umemura
Journal:  Molecules       Date:  2021-12-03       Impact factor: 4.411

6.  Miniaturized catalysis: monolithic, highly porous, large surface area capillary flow reactors constructed in situ from polyhedral oligomeric silsesquioxanes (POSS).

Authors:  P Scholder; I Nischang
Journal:  Catal Sci Technol       Date:  2015-06-17       Impact factor: 6.119

7.  Continuous-flow Heck synthesis of 4-methoxybiphenyl and methyl 4-methoxycinnamate in supercritical carbon dioxide expanded solvent solutions.

Authors:  Phei Li Lau; Ray W K Allen; Peter Styring
Journal:  Beilstein J Org Chem       Date:  2013-12-17       Impact factor: 2.883

  7 in total

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