Literature DB >> 15822996

Efficient synthesis of tribenzohexadehydro[12]annulene and its derivatives in the ionic liquid.

Yang Li1, Jiyong Zhang, Wenkuan Wang, Qiang Miao, Xuegong She, Xinfu Pan.   

Abstract

A simple and efficient synthesis of tribenzohexadehydro[12]annulene and related derivatives in the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate is described. A Sonogashira coupling reaction is the key step. In this system, the amount of CuI normally used can be reduced so that homocoupling is minimized.

Entities:  

Year:  2005        PMID: 15822996     DOI: 10.1021/jo047836v

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Synthesis of 5-(2-methoxy-1-naphthyl)- and 5-[2-(methoxymethyl)-1-naphthyl]-11H-benzo[b]fluorene as 2,2'-disubstituted 1,1'-binaphthyls via benzannulated enyne-allenes.

Authors:  Yu-Hsuan Wang; Joshua F Bailey; Jeffrey L Petersen; Kung K Wang
Journal:  Beilstein J Org Chem       Date:  2011-04-19       Impact factor: 2.883

  1 in total

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