Literature DB >> 15816750

A chelation effect on the pathway between intramolecular hydrodimerization and pinacol coupling.

Scott T Handy1, Duncan Omune.   

Abstract

[structure: see text] Depending upon the reaction conditions, the reductive cyclization affords either the pinacol or normal hydrodimerization-type products. This selectivity is highly dependent upon the substitution at the beta-position of the enones.

Entities:  

Year:  2005        PMID： 15816750     DOI： 10.1021/ol0502026

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance.

Authors:  Ming Yan; Yu Kawamata; Phil S Baran
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

2.  Diastereoselective synthesis of cyclopentanediols by InCl 3/Al mediated intramolecular pinacol coupling reaction in aqueous media.

Authors:  Yunhua Chen; Jieping Wan; Chunyan Wang; Cuirong Sun
Journal:  Molecules       Date:  2008-10-27       Impact factor: 4.411
  2 in total

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