| Literature DB >> 15796509 |
Dragoslav Vidovic1, Jennifer A Moore, Jamie N Jones, Alan H Cowley.
Abstract
The first example of a stable oxoborane monomer (LB=O) stabilized by complexation to AlCl3 has been prepared by the reaction of LAlCl2 with BCl3 followed by treatment with H2O in CH2Cl2 (L = [HC(CMe)2(NC6F5)2]). DFT calculations reveal that considerable boron-oxygen double bond character is retained in this complex.Entities:
Year: 2005 PMID： 15796509 DOI： 10.1021/ja0507564
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419