Literature DB >> 15792444

A tris(mu-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue.

Liviu M Mirica1, T Daniel P Stack.   

Abstract

The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(mu-hydroxy)tricopper(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.

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Year:  2005        PMID: 15792444     DOI: 10.1021/ic048182b

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  8 in total

1.  Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex.

Authors:  Debabrata Maiti; Julia S Woertink; Reza A Ghiladi; Edward I Solomon; Kenneth D Karlin
Journal:  Inorg Chem       Date:  2009-09-07       Impact factor: 5.165

Review 2.  Activation of dioxygen by copper metalloproteins and insights from model complexes.

Authors:  David A Quist; Daniel E Diaz; Jeffrey J Liu; Kenneth D Karlin
Journal:  J Biol Inorg Chem       Date:  2016-12-05       Impact factor: 3.358

Review 3.  Copper active sites in biology.

Authors:  Edward I Solomon; David E Heppner; Esther M Johnston; Jake W Ginsbach; Jordi Cirera; Munzarin Qayyum; Matthew T Kieber-Emmons; Christian H Kjaergaard; Ryan G Hadt; Li Tian
Journal:  Chem Rev       Date:  2014-03-03       Impact factor: 60.622

Review 4.  Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Authors:  Courtney E Elwell; Nicole L Gagnon; Benjamin D Neisen; Debanjan Dhar; Andrew D Spaeth; Gereon M Yee; William B Tolman
Journal:  Chem Rev       Date:  2017-01-19       Impact factor: 60.622

5.  Ground-state electronic and magnetic properties of a mu3-oxo-bridged trinuclear Cu(II) complex: correlation to the native intermediate of the multicopper oxidases.

Authors:  Jungjoo Yoon; Edward I Solomon
Journal:  Inorg Chem       Date:  2005-10-31       Impact factor: 5.165

6.  Multireference ab initio calculations of g tensors for trinuclear copper clusters in multicopper oxidases.

Authors:  Steven Vancoillie; Jakub Chalupský; Ulf Ryde; Edward I Solomon; Kristine Pierloot; Frank Neese; Lubomír Rulísek
Journal:  J Phys Chem B       Date:  2010-06-10       Impact factor: 2.991

7.  O2 reduction to H2O by the multicopper oxidases.

Authors:  Edward I Solomon; Anthony J Augustine; Jungjoo Yoon
Journal:  Dalton Trans       Date:  2008-05-07       Impact factor: 4.390

8.  μ-Bromido-bis{μ-2,2'-[4,7-diaza-decane-1,10-diylbis(nitrilo-methanylyl-idene)]diphenolato}tricopper(II) bromide dimethyl-formamide disolvate.

Authors:  Gervas Assey; Ray J Butcher; Yilma Gultneh
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-08-06
  8 in total

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