| Literature DB >> 15787505 |
Thomas A Dineen1, William R Roush.
Abstract
[reaction: see text] The racemic cis-decalin core fragment 30 of integramycin was synthesized by a sequence involving a highly diastereoselective intramolecular Diels-Alder reaction of triene 24. A remarkable switch in stereoselectivity occurred upon changing the dienophile unit of 24 from (Z)- to (E)-geometry.Entities:
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Year: 2005 PMID： 15787505 DOI： 10.1021/ol050191g
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005