Literature DB >> 15771483

A hydrophobic nanocapsule controls the photophysics of aromatic molecules by suppressing their favored solution pathways.

Lakshmi S Kaanumalle1, Corinne L D Gibb, Bruce C Gibb, V Ramamurthy.   

Abstract

A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Remarkably, anthracene that dimerizes with unit efficiency in solution does not dimerize within the capsule despite forming 2:2 complex. The capsule allows an unprecedented examination of the anthracene excimer.

Entities:  

Year:  2005        PMID： 15771483     DOI： 10.1021/ja0425381

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Kinetic resolution of constitutional isomers controlled by selective protection inside a supramolecular nanocapsule.

Authors:  Simin Liu; Haiying Gan; Andrew T Hermann; Steven W Rick; Bruce C Gibb
Journal:  Nat Chem       Date:  2010-08-08       Impact factor: 24.427

2.  Molecular recognition and self-assembly special feature: Disproportionation and self-sorting in molecular encapsulation.

Authors:  Dariush Ajami; Jun-Li Hou; Trevor J Dale; Elizabeth Barrett; Julius Rebek
Journal:  Proc Natl Acad Sci U S A       Date:  2009-02-27       Impact factor: 11.205

Review 3.  High-definition self-assemblies driven by the hydrophobic effect: synthesis and properties of a supramolecular nanocapsule.

Authors:  Simin Liu; Bruce C Gibb
Journal:  Chem Commun (Camb)       Date:  2008-06-06       Impact factor: 6.222

4.  Photophysics Applied to Cavitands and Capsules.

Authors:  Orion B Berryman; Henry Dube; Julius Rebek
Journal:  Isr J Chem       Date:  2011-07-01       Impact factor: 3.333

5.  An improved synthesis of 'octa-acid' deep-cavity cavitand.

Authors:  Simin Liu; Sarah E Whisenhunt-Ioup; Corinne L D Gibb; Bruce C Gibb
Journal:  Supramol Chem       Date:  2011-01-01       Impact factor: 1.688

6.  Guests of Differing Polarities Provide Insight into Structural Requirements for Templates of Water-Soluble Nano-Capsules.

Authors:  Corinne L D Gibb; Bruce C Gibb
Journal:  Tetrahedron       Date:  2009-08-29       Impact factor: 2.457

7.  Interaction energies and dynamics of acid-base pairs isolated in cavitands.

Authors:  Byron W Purse; Sara M Butterfield; Pablo Ballester; Alexander Shivanyuk; Julius Rebek
Journal:  J Org Chem       Date:  2008-08-02       Impact factor: 4.354

Review 8.  Chemistry and catalysis in functional cavitands.

Authors:  Richard J Hooley; Julius Rebek
Journal:  Chem Biol       Date:  2009-03-27

9.  Self-assembled capsules of unprecedented shapes.

Authors:  Konrad Tiefenbacher; Dariush Ajami; Julius Rebek
Journal:  Angew Chem Int Ed Engl       Date:  2011-08-26       Impact factor: 15.336

10.  Supramolecular-induced regiocontrol over the photochemical [4 + 4] cyclodimerization of NHC- or azole-substituted anthracenes.

Authors:  Sha Bai; Li-Li Ma; Tao Yang; Fang Wang; Li-Feng Wang; F Ekkehardt Hahn; Yao-Yu Wang; Ying-Feng Han
Journal:  Chem Sci       Date:  2020-12-17       Impact factor: 9.825
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