Literature DB >> 15770266

Steric engineering of C-F activation with lanthanoid formamidinates.

Marcus L Cole1, Glen B Deacon, Peter C Junk, Kristina Konstas.   

Abstract

Reaction of lanthanum with Hg(C6F5)2 and bulky N,N'-bis(2,6-diisopropylphenyl)formamidine (HDippForm) in tetrahydrofuran gives [LaF{DippForm}2(THF)] with a rare terminal Ln-F bond, and a high yield of a novel functionalized formamidine, DippForm((CH2)4OC6F4H-o).

Entities:  

Year:  2005        PMID: 15770266     DOI: 10.1039/b419047e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Rare Earth Starting Materials and Methodologies for Synthetic Chemistry.

Authors:  Fabrizio Ortu
Journal:  Chem Rev       Date:  2022-01-31       Impact factor: 60.622

2.  N-Ethyl-N-phenyl-N'-tosyl-formamidine.

Authors:  Heng-Shui Shen; Nan Liu; Zi-Cheng Li; Wen-Cai Huang
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-06-17
  2 in total

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