Literature DB >> 15760120

Convenient method for epoxidation of alkenes using aqueous hydrogen peroxide.

Man Kin Tse1, Markus Klawonn, Santosh Bhor, Christian Döbler, Gopinathan Anilkumar, Herbert Hugl, Wolfgang Mägerlein, Matthias Beller.   

Abstract

[reaction: see text] The complex [Ru(tpy)(pydic)] (1a) is an active catalyst for epoxidation of alkenes by aqueous 30% hydrogen peroxide in tertiary alcohols. The protocol is simple to operate and gives the corresponding epoxides in good to excellent yields. Chiral enantiopure [Ru(tpy)(pydic)] complexes have been synthesized and successfully applied in this procedure.

Entities:  

Year:  2005        PMID： 15760120     DOI： 10.1021/ol047604i

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Synthesis and Applications of (ONO Pincer)Ruthenium-Complex-Bound Norvalines.

Authors:  Katsuhiro Isozaki; Tomoya Yokoi; Ryota Yoshida; Kazuki Ogata; Daisuke Hashizume; Nobuhiro Yasuda; Koichiro Sadakane; Hikaru Takaya; Masaharu Nakamura
Journal:  Chem Asian J       Date:  2016-03-07

2.  Site-selective unidirectional benzylic sp3 C-H oxidation of dodecahydrotriphenylene with RuCl3-NaIO4: formation of benzylic ketones.

Authors:  Gaurang J Bhatt; Pradeep T Deota; Deepak Upadhyay; Prafulla K Jha
Journal:  RSC Adv       Date:  2021-10-20       Impact factor: 3.361
  2 in total

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