Literature DB >> 15743212

Photoelectron spectroscopy of chromium-doped silicon cluster anions.

Weijun Zheng1, J Michael Nilles, Dunja Radisic, Kit H Bowen.   

Abstract

The photoelectron spectra of chromium-doped silicon cluster anions, CrSi-(n), were measured over the size range, n=8-12. Their vertical detachment energies were measured to be 2.71, 2.88, 2.87, 2.95, and 3.18 eV, respectively. Our results support theoretical calculations by Khanna, Rao, and Jena [Phys. Rev. Lett. 89, 016803 (2002)] which found CrSi12 to be an enhanced stability (magic) cluster with its chromium atom encapsulated inside a silicon cage and with its magnetic moment completely quenched by the effects of the surrounding cage.

Entities:  

Year:  2005        PMID： 15743212     DOI： 10.1063/1.1851984

Source DB:  PubMed          Journal:  J Chem Phys        ISSN： 0021-9606            Impact factor:   3.488


  4 in total

Review 1.  Clusters: a bridge across the disciplines of environment, materials science, and biology.

Authors:  A W Castleman; Puru Jena
Journal:  Proc Natl Acad Sci U S A       Date:  2006-07-11       Impact factor: 11.205

2.  Probing the electronic structures and properties of neutral and anionic ScSi(n)((0,-1)) (n = 1-6) clusters using ccCA-TM and G4 theory.

Authors:  Jun Lu; Jucai Yang; Yali Kang; Hongmei Ning
Journal:  J Mol Model       Date:  2014-02-11       Impact factor: 1.810

3.  Multiple valence superatoms.

Authors:  J U Reveles; S N Khanna; P J Roach; A W Castleman
Journal:  Proc Natl Acad Sci U S A       Date:  2006-11-22       Impact factor: 11.205

4.  Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3-, [Rh@Sn12]3-, [Rh2@Sn17]6- and the first triply-fused stannide, [Rh3@Sn24]5.

Authors:  Chao Liu; Xiao Jin; Lei-Jiao Li; Jun Xu; John E McGrady; Zhong-Ming Sun
Journal:  Chem Sci       Date:  2019-03-11       Impact factor: 9.825
  4 in total

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