Literature DB >> 15742064

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex.

Yong-Chua Teo1, Kui-Thong Tan, Teck-Peng Loh.   

Abstract

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

Entities:  

Year:  2005        PMID: 15742064     DOI: 10.1039/b412736f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Application of tandem ring-closing enyne metathesis: formal total synthesis of (-)-cochleamycin A.

Authors:  Sumit Mukherjee; Daesung Lee
Journal:  Org Lett       Date:  2009-07-02       Impact factor: 6.005

  1 in total

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