Literature DB >> 15732957

Reaction of LAlH2 with tert-butyl hydrogenperoxide under C-H Bond activation and substitution leads to the formation of a pentacoordinated tert-butylperoxo aluminum compound.

S Shravan Kumar1, Sanjay Singh, Herbert W Roesky, Jörg Magull.   

Abstract

The reaction between beta-diketiminato-stabilized aluminum dihydride LAlH2 and tBuOOH leads to the formation of a pentacoordinated tert-butylperoxo aluminum compound.

Entities:  

Year:  2005        PMID: 15732957     DOI: 10.1021/ic048336n

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  [N,N-Bis(2,6-diisopropyl-phen-yl)pent-2-ene-2,4-diiminato(1-)]bis-(1,2,4-diaza-phosphol-1-yl)aluminium(III).

Authors:  Dongming Yang; Chengfu Pi; Yuqiang Ding; Wenjun Zheng
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-27
  1 in total

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