| Literature DB >> 15730304 |
José L García Ruano1, M Angeles Fernández-Ibáñez, M Carmen Maestro, M Mercedes Rodríguez-Fernández.
Abstract
The reduction of delta-ketosulfoxides constitutes the first evidence of the efficiency of the sulfinyl group to control the stereoselectivity of 1,5-asymmetric induction processes. The use of DIBAL/Yb(OTf)3 or L-Selectride as the reducing agents provides delta-hydroxysulfoxides with the opposite configuration at the hydroxylic carbon in a highly stereoselective way.Entities:
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Year: 2005 PMID： 15730304 DOI： 10.1021/jo047999j
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354