| Literature DB >> 15730287 |
Yong-Gui Zhou1, Peng-Yu Yang, Xiu-Wen Han.
Abstract
Highly enantioselective hydrogenation of exocyclic enamides, (Z)-3-arylidene-4-acyl-3,4-dihydro-2H-benzoxazines, was achieved in up to 98.6% ee by using Rh/(R,R)-Me-Duphos complex as the catalytic system. The absolute configuration of the product was assigned as R by chemical interrelations.Entities:
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Year: 2005 PMID： 15730287 DOI： 10.1021/jo048212s
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354