| Literature DB >> 15713071 |
Mark R Crimmin1, Ian J Casely, Michael S Hill.
Abstract
The calcium-catalyzed intramolecular hydroamination of alkenes and alkynes is reported. The beta-diketiminato complex [{HC(C(Me)2N-2,6-iPr2C6H3)2}-Ca{N(SiMe3)2}(THF)] affects catalytic cyclization of a range of aminoalkenes and aminoalkynes with activities that are broadly commensurate to those of established rare earth catalysts.Entities:
Year: 2005 PMID： 15713071 DOI： 10.1021/ja043576n
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419