| Literature DB >> 15704925 |
Jorge García-Fortanet1, John R Debergh, Jef K De Brabander.
Abstract
Herein, we propose a modular and general strategy to construct orcinol-type depsides based on the photolysis of functionalized benzodioxinones (I). Notably, resorcinylic esters are obtained without competing isocoumarin (II) formation, exemplified by the first total synthesis of gustastatin in 10 steps from commercially available trihydroxybenzoic acid. [Structure: see text]Entities:
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Year: 2005 PMID： 15704925 DOI： 10.1021/ol047507p
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005